Van der Waals Isotherms 1.16


An equation of state is a mathematical relation between pressure, molar volume, and temperature of a system. In the graph below, van der Waals equation of state isotherms are calculated. The axes are labeled with the reduced pressure, p / pc, and reduced volume, V / Vc, where pc = a / 27b2 and Vc = 3b. The individual isotherms are calculated with the reduced temperature, T / Tc, where Tc = 8a / 27Rb.

The formula is

Where the isotherms are plotted using reduced variables pr = p / pc, Vr = V / Vc, and Tr = T / Tc.

To graph pr enter the parameter (i.e., Tr) and hit New Plot. Up to 5 plots can be displayed at one time. The Clear button will remove all plots. To see the parameters for each plot hit the Legend on/off button. The Redraw button will refresh the graph. This is useful when the function domain (i.e., Vr ) has been changed. To see the value of each plot at a given point, move your cursor to the desired location then click and hold. Note: The Vr axis is plotted on a base 10 logarithmic scale.